Jones, A. A., California Institute of Technology, Pasadena, USA, email@example.com
Sessions, A. L., California Institute of Technology, Pasadena, USA, firstname.lastname@example.org
Schimmelmann, A. ., Indiana University, Bloomington, USA, email@example.com
Sauer, P. ., Indiana University, Bloomington, USA, firstname.lastname@example.org
Topalov, K. ., Indiana University, Bloomington, USA, email@example.com
As marine particulate organic matter (POM) is transported to the deep ocean, it is chemically altered such that much of it becomes unidentifiable at the molecular level. Because it can compose the large majority of POM in deep waters, understanding the source of this molecularly unidentifiable material is important to building a detailed, mechanistic model of carbon export to sediments. A proxy for the unidentifiable organic matter is the fraction remaining after hydrolysis in 6 M HCl - the acid-insoluble (AI) fraction. Previous investigations into bulk properties of the AI fraction have resulted in conflicting hypotheses on the biochemical source(s) of this material: is it carbohydrate-like, lipid-like, or a transformed mixture of other compounds? Because D/H ratios vary between biochemical classes to a greater extent than other isotopic signatures, the determination of &deltaD in the AI fraction could help constrain its source more precisely. Here we will present a new approach to measuring the D/H ratios of nonexchangeable hydrogen in bulk organic fractions, together with the first measured &deltaD values for the AI fraction from POM.
Time: 18:00 - 20:00
Presentation is given by student: Yes